The Ward group has prepared lamellar hydrogen-bonded frameworks with organic “pillars”. Certain crystalline compounds in this family with lamellar architectures form both smectic liquid crystal phases and organogels, and compounds based on hexagonal arrays of hydrogenbonded cylindrical nanotubes have been observed, suggesting an interesting connection between organic crystals and soft matter microstructures.


SESMI students will be introduced to crystal engineering concepts by synthesizing molecular building blocks and crystallizing new materials. They also will be introduced to X-ray diffraction methods for solid-state structure determination